Mass-spectrometric investigation of 3-acylindole oximes

Autor: Terent'ev, P. B., Druzhinina, V. V., Yurovskaya, M. A.
Zdroj: Chemistry of Heterocyclic Compounds; June 1983, Vol. 19 Issue: 6 p635-638, 4p
Abstrakt: Fragmentation pathways that are due to fragmentation of the oximine grouping and are typical for all of the oximes, and lead to [M-OH]+, [M-NHOH]+, and [M-C(R3)-NOH]+ ions are characteristic for the mass spectra of 3-acylindole oximes. In addition, the presence of a nucleophilic indole ring leads to a number of specific rearrangement processes, particularly to the Beckmann rearrangement.
Databáze: Supplemental Index