| Autor: |
Oshis, Ya. F., Anderson, A. A., Shimanskaya, M. V. |
| Zdroj: |
Chemistry of Heterocyclic Compounds; July 1982, Vol. 18 Issue: 7 p740-745, 6p |
| Abstrakt: |
The transformations of 1,3-diaminopropane and 3-amino-1-propanol under pulse conditions over tungsten trioxide in an inert atmosphere at 300–500 °C were investigated. The transformation of 1,3-diaminopropane leads to the formation of saturated pyrimidine bases; the maximum selectivity of the formation of hexahydropyrimidine bases at 300 °C is 60%, while the selectivity of the formation of tetrahydropyrimidine bases is 20% (400 °C). In the case of 3-amino-1-propanol the overall yield of heterocyclic bases was less than 5%, and piperazine and pyrazine derivatives were observed as the cyclic products; the formation of pyrimidine bases was not observed. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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