Synthesis, electronic structure, and physicochemical characteristics of pyrazolo[1,2-a]pyridazinium

Autor: Voshula, V. N., Vysotskii, Yu. B., Seraya, V. I., Novikova, N. T., Mushii, R. Ya., Dulenko, V. I.
Zdroj: Chemistry of Heterocyclic Compounds; December 1990, Vol. 26 Issue: 12 p1349-1357, 9p
Abstrakt: The interaction of 1-methallylpyrazoles with acetic or propionic anhydride in the presence of perchloric acid forms products of acylation at the double bond and subsequent heterocyclization — pyrazolo[1,2-a]pyridazinium salts — that are representatives of a new heteroaromatic system. Analogous cyclization is observed in the acylation of 3-(2-hydroxy-2-methylpropyl-pyrazole.
Databáze: Supplemental Index