Reaction of 9-amino(phenylamino)methylene- and 9-α-aminobenzylidene-4-azafluorenes with some electrophilic reagents

Autor: Varlamov, A. V., Levov, A. N., Davydov, V. V., Aliev, A. É., Krapivko, A. P., Sheban, G. V., Skomorokhova, A. I., Zaitsev, B. E., Prostakoy, N. S.
Zdroj: Chemistry of Heterocyclic Compounds; April 1995, Vol. 31 Issue: 4 p461-467, 7p
Abstrakt: It was shown that initial protonation of 9-aminomethylene-4-azafluorene takes place at the pyridine nitrogen atom. In nitrosation of this azafluorene, 4-azafluorenone oxime is formed, and in reaction with dichlorocarbene, 1'-amino-2', 2'-dichlorospiro[4-azafluorene-9,3'-cyclopropane] is formed. Acylation yields mono- or diacyl derivatives as a function of the acylating agent and reaction conditions.
Databáze: Supplemental Index