Autor: |
Varlamov, A. V., Levov, A. N., Davydov, V. V., Aliev, A. É., Krapivko, A. P., Sheban, G. V., Skomorokhova, A. I., Zaitsev, B. E., Prostakoy, N. S. |
Zdroj: |
Chemistry of Heterocyclic Compounds; April 1995, Vol. 31 Issue: 4 p461-467, 7p |
Abstrakt: |
It was shown that initial protonation of 9-aminomethylene-4-azafluorene takes place at the pyridine nitrogen atom. In nitrosation of this azafluorene, 4-azafluorenone oxime is formed, and in reaction with dichlorocarbene, 1'-amino-2', 2'-dichlorospiro[4-azafluorene-9,3'-cyclopropane] is formed. Acylation yields mono- or diacyl derivatives as a function of the acylating agent and reaction conditions. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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