Structures of bis(cyclopentadienyl) binuclear titanium complexes

Autor: Mkoyan, Sh. G., Aliev, Z. G., Urazovskii, I. F., Atovmyan, L. O., Nifant'ev, I. E., Butakov, K. A.
Zdroj: Russian Chemical Bulletin; September 1996, Vol. 45 Issue: 9 p2154-2156, 3p
Abstrakt: The (C5H4-XMe2-C5H4) · (TiCl3)2 binuclear complexes, where X = Si (1) or C (2), have been studied by X-ray structural analysis. In both structures, the coordination polyhedra about the Ti atoms are distorted tetrahedra formed by three CI atoms and one Cp ring. The conformations of molecules1 and2 and the possibility of the occurrence of secondary Ti-Cp...Cl-Ti interaction are discussed
Databáze: Supplemental Index