| Autor: |
Kolesnichenko, N. V., Sharikova, M. V., Marzabekova, T. Kh., Markova, N. A., Slivinskii, E. V. |
| Zdroj: |
Russian Chemical Bulletin; August 1996, Vol. 45 Issue: 8 p1866-1869, 4p |
| Abstrakt: |
Approaches to increasing the selectivity of water-soluble catalytic systems based on RhCl3 and polycation in hydroformylation of hex- 1-ene were studied. The introduction of a long-chain alkyl radical into the polycation or the use of a higher fatty acid anion results in an increase in the selectivity of the catalytic system at pH > 7 with respect to n-aldehyde to 60 %. This effect is presumably associated with the suppression of isomerization processes due to steric hindrances. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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