Molecular structure of 6,6-dimethyl-2-dimethylamino-2-oxo-4,5; 7,8-dibenzo-1,3,6,2-dioxasilaphosphocin and 2-methyl-2,6-dioxo-4,5; 7,8-dibenzo-1,3,2-dioxaphosphocin

Autor: Litvinov, I. A., Kataeva, O. N., Naumov, V. A., Kadyrov, R. A., Anonimova, I. V., Khainike, I., Arshinova, R. P.
Zdroj: Russian Chemical Bulletin; February 1992, Vol. 41 Issue: 2 p248-253, 6p
Abstrakt: An x-ray structural investigation of the synthesized title compounds (1) and (2) has been performed. The heterocycle of 1 has a boat-chair conformation with the P2=O2 bond in the axial position. The heterocycle of 2 has a distorted-boat conformation with the C6=O carbonyl in the plane of one of the fused benzene rings. The P2=O2 bond is in a pseudoequatorial position.
Databáze: Supplemental Index