Conversions of hydrocarbons treated with neodymium metal under the conditions of mechanochemical activation at room temperature

Autor: Dolgoplosk, B. A., Vakovlev, V. A., Tinyakova, E. I., Gol'shtein, S. B., Bondarenko, G. N.
Zdroj: Russian Chemical Bulletin; June 1996, Vol. 45 Issue: 6 p1316-1320, 5p
Abstrakt: The conversions of cyclohexene and 1,3- and 1,4-cyclohexadiencs treated with neodymium metal under the conditions of mechanochemical activation at 20 °C have been studied. A complicated cycle of conversions, including isomerization, disproportionation, and polymerization, occurs under the reaction conditions. A mechanism for the conversion of the hydrocarbons involving organornetallic intermediates is proposed.
Databáze: Supplemental Index
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