Reaction of 1-aryl-2-alkenyldiazene 1-oxides with hydrogen chloride. Novel approach to the synthesis of functionally substituted arylhydrazones

Autor: Tyurin, A. Yu., Churakov, A. M., Goncharova, E. L., Ioffe, S. L., Strelenko, Yu. A., Tartakovsky, V. A.
Zdroj: Russian Chemical Bulletin; May 1995, Vol. 44 Issue: 5 p901-906, 6p
Abstrakt: The reaction of 1-aryl-2-alkenyldiazene 1-oxides with HCl yields arylhydrazones of a-chloroacyl chlorides, which eliminate HCl to give 1-aryl-2-(1-chloroalken-1-yl)diazenes. The latter add amines, alcohols, and carboxylic acids to give arylhydrazone chlorides with a-functional groups.
Databáze: Supplemental Index