Preparation and reactivity of metal-containing monomers

Autor: Kitsenko, N. A., Ishkov, Yu. V., Voloshanovskii, I. S., Aliev, Z. G., Pomogailo, A. D.
Zdroj: Russian Chemical Bulletin; September 1995, Vol. 44 Issue: 9 p1758-1763, 6p
Abstrakt: Vinylporphyrins containing one vinyl group at the pyrrole or benzene ring and their complexes with Cu2+ and Zn2+ have been obtained by the Wittig reaction. Compounds obtained were characterized by physicochemical methods. X-ray diffraction analysis of 5-(4-vinylphenyl)-10,15,20-triphenylporphyrin has been carried out. It is likely that the inclusion of the vinyl group is accompanied by weak electron effects on the macrocycle. No nonequivalence of N-H bonds is observed in initial macrocycles.
Databáze: Supplemental Index