Structure of products of the reaction of 2-cyanoaziridine with carbonyl compounds

Autor: Koehler, K. F., Zaddach, H., Kadorkina, G. K., Voznesenskii, V. N., Chervin, I. I., Kostyanovsky, R. G.
Zdroj: Russian Chemical Bulletin; December 1993, Vol. 42 Issue: 12 p2049-2052, 4p
Abstrakt: The structure of azimexone (3), the product of the reaction of 2-cyanoaziridine with acetone, was confirmed on the basis of1H and13C NMR spectra. The formation of this product is accounted for by the a-aziridinoalkylating action of an intermediate containing a good leaving iminoyloxy group. Similar reactions were observed for 1-chloromethylaziridine and a 1-aziridinylmethylammonium salt (6), but not for 1-methoxymethylaziridine (7) and 1-aziridinemethanol.
Databáze: Supplemental Index