Auration of ruthenocene: synthesis and molecular structure of mono- and diaurated derivatives

Autor: Nefedova, M. N., Mamed'yarova, I. A., Sokolov, V. I., Smyslova, E. I., Kuz'mina, L. G., Grandberg, K. I.
Zdroj: Russian Chemical Bulletin; July 1994, Vol. 43 Issue: 7 p1275-1277, 3p
Abstrakt: Ruthenocene, like ferrocene, reacts with (Ph3PAu)3O+BF4- to afford agem-diaurated derivative CpRuC5H4(AuPPh3)2+BF4-, which is converted into CpRuC5H4AuPPh3 when treated with PPh3. X-ray structural analysis revealed substantial Ru-Au interaction in the diaurated derivative.
Databáze: Supplemental Index