Synthesis of derivatives of ketocarboxylic acids by the decomposition of 1,4-cyclohexanedione monoethyleneketal hydroperoxide

Autor: Starostin, E. K., Mazurchik, A. A., Ignatenko, A. V., Nikishin, G. I.
Zdroj: Russian Chemical Bulletin; July 1993, Vol. 42 Issue: 7 p1174-1178, 5p
Abstrakt: The decomposition of 1,4-dihydroxy-1,4-dihydroperoxycyclohexane under the action of FeSO4 and the decomposition of 1,4-cyclohexanedione monoethyleneketal hydroperoxide under the action of FeII salts in the presence of various ligands or under the action of CuII sulfate have been studied. A preparative method for the synthesis of derivatives of diketodicarboxylic or ?-functionally substituted ketocarboxylic acids from 1,4-cyclohexanedione monoethyleneketal has been developed.
Databáze: Supplemental Index
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