Isomerism in metal complexes of 1,3,5-diazaphosphorinanes. Synthesis, crystal and molecular structure of conformers ofcis-bis(1,3,5-triphenyl-1,3,5-triazaphosphorinane)dichloroplatinum(II)

Autor: Karasik, A. A., Bobrov, S. V., Nikonov, G. N., Litvinov, I. A., Naumov, V. A., Akhmadullin, A. G.
Zdroj: Russian Chemical Bulletin; September 1993, Vol. 42 Issue: 9 p1587-1592, 6p
Abstrakt: The crystal and molecular structures were determined for two individual conformers ofcis-bis(1,3,5-triphenyl-1,3,5-diazaphosphorinane)dichloroplatinum(II) differing in the rotation of the heterocyclic ligand planes around the P-Pt bond and in the orientation of the substituents at the phosphorus atoms in the ligands.
Databáze: Supplemental Index