Synthesis of heterocyclic azoxy compounds from C-nitroheterocyclic compounds and metal derivatives oftert-butylamine

Autor: Apasov, É. T., Shepelev, E. V., Dzhetigenov, B. A., Strelenko, Yu. A., Kalinin, A. V., Tartakovskii, V. A.
Zdroj: Russian Chemical Bulletin; July 1992, Vol. 41 Issue: 7 p1280-1281, 2p
Abstrakt: The reaction of 3-nitropyrazole and 3(5)-nitro-1,2,4-triazole with t-BuNHMgBr gives the corresponding asymmetrical diazene oxides. Furthermore, 3(5)-(1,1-dimethylethyl)azoxy-1,2,4-triazole was also synthesized by the reaction of 1-trimethylsilyl-3(5)-nitro-1,2,4-triazole with t-BuNHLi.
Databáze: Supplemental Index