| Autor: |
Gursky, M. E., Golovin, S. B., Ignatenko, A. V., Bubnov, Yu. N. |
| Zdroj: |
Russian Chemical Bulletin; January 1993, Vol. 42 Issue: 1 p139-143, 5p |
| Abstrakt: |
(2,3-Dimethylenetetramethylene)bis(dipropylborane) (1) prepared by borylation of 2,3-dimethylbutadienediyl dipotassium reacts with ketones to form symmetrical diols in a yield of 46–73%. [4+2]-Cycloaddition reactions of diborane1 with 1,2-dicarbonyl compounds proceed highly stereospecifically, affording onlycis-isomers of 4,5-dimethylenecyclohexane1, 2-diols. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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