Fluorinated ketones in the Baylis-Hillman reaction
Autor: | Golubev, A. S., Galakhov, M. V., Kolomiets, A. F., Fokin, A. V. |
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Zdroj: | Russian Chemical Bulletin; December 1992, Vol. 41 Issue: 12 p2193-2196, 4p |
Abstrakt: | Hexafluoroacetone, bromopentafluoroacetone, 1,3-dichloro-1,1,3,3-tetrafluoroacetone, and trifluoropyruvic acid methyl ester react with ethyl acrylate, acrylonitrile, acrolein, and methyl vinyl ketone in the presence of 1,4-diazabicyclo[2,2,2]octane with the formation of a-alkylation products. |
Databáze: | Supplemental Index |
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