Fluorinated ketones in the Baylis-Hillman reaction

Autor: Golubev, A. S., Galakhov, M. V., Kolomiets, A. F., Fokin, A. V.
Zdroj: Russian Chemical Bulletin; December 1992, Vol. 41 Issue: 12 p2193-2196, 4p
Abstrakt: Hexafluoroacetone, bromopentafluoroacetone, 1,3-dichloro-1,1,3,3-tetrafluoroacetone, and trifluoropyruvic acid methyl ester react with ethyl acrylate, acrylonitrile, acrolein, and methyl vinyl ketone in the presence of 1,4-diazabicyclo[2,2,2]octane with the formation of a-alkylation products.
Databáze: Supplemental Index