gem-Dinitro compounds in organic synthesis. 1. Synthesis of functionally substituted polynitro compounds with the use of the universal synthon, ethyl dinitroacetate
| Autor: | Laikhter, A. L., Cherkasova, T. I., Mel'nikova, L. G., Ugrak, B. I., Fainzil'berg, A. A., Semenov, V. V. |
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| Zdroj: | Russian Chemical Bulletin; August 1991, Vol. 40 Issue: 8 p1637-1643, 7p |
| Abstrakt: | Ethyl nitroacetate (I) was used as a synthon in the preparation of dinitromethane, dinitroacetic acid, 2,2-dinitroethanol, fluorodinitromethane, 1,1,3,3-tetranitropropane, and some condensation products of Henry and Mannich reactions. A number of dinitroacetaldehyde derivatives were also prepared: its potassium salt, oxime, and hydrazone, dinitroacetaldehyde azine, and mixed azines with other acetaldehydes. |
| Databáze: | Supplemental Index |
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