Synthesis of 1-phenyl-3,3-dimethyltriazene 2-oxide and the corresponding triazene from nitro compounds and N-magnesium bromides

Autor: Apasov, É. T., Dzhetigenov, B. A., Kalinin, A. V., Tartakovskii, V. A.
Zdroj: Russian Chemical Bulletin; June 1991, Vol. 40 Issue: 6 p1289-1291, 3p
Abstrakt: The reaction of dimethylnitramine with Ph-N(MgBr)2 gives 1-phenyl-3,3-dimethyl-triazene 2-oxide, which is the first reported triazene 2-oxide. The reaction of nitrobenzene with Me2NNHMgBr gives only the corresponding triazene.
Databáze: Supplemental Index