Study of the chemical mechanism for the aging of the fischer reagent

Autor: Kil'yanov, M. Yu., Petrov, S. I.
Zdroj: Russian Chemical Bulletin; August 1990, Vol. 39 Issue: 8 p1731-1733, 3p
Abstrakt: 1H and13C NMR spectroscopy were used to show that alkylation of the nitrogen atom in pyridine by dimethyl sulfate proceeds with the formation of N-methylpyridinium methyl sulfate in the Fischer reagent upon use and during storage along with other reactions already described in the literature.
Databáze: Supplemental Index