Electrochemical alkylation of 2,2′-dipyridylamine

Autor: Dorokhov, V. A., Baryshnikova, T. K., Gordeev, M. F., Niyazymbetov, M. E., Petrosyan, V. A.
Zdroj: Russian Chemical Bulletin; January 1991, Vol. 40 Issue: 1 p138-141, 4p
Abstrakt: A method was developed for preparation of alkyl-(2,2'-dipyridyl) amines, consisting of the reaction of alkyl halides with the N anion electrochemically generated from 2,2'-dipyridylamine. The alkylation occurs regiospecifically, and CH2Cl2 can also be used as the methylating agent. Complexes of alkyl-(2,2'-dipyridyl)-amines with Pd(2+) and Cu(2+) salts were obtained.
Databáze: Supplemental Index