Thermal changes in decahydro-closo-decaborate(2-)copper(I) Cu2B10H10 and the nature of copper borides

Autor: Volkov, V. V., Yur'ev, G. S., Solomatina, L. Ya., Voronina, G. S., Myakishev, K. G.
Zdroj: Russian Chemical Bulletin; March 1990, Vol. 39 Issue: 3 p435-438, 4p
Abstrakt: Thermal changes in Cu2B10H10 have been studied over the temperature range 25–800‡C using DTA, gas-volume, IR-spectroscopic, and x-ray phase analytical methods. Decomposition of the salt starts at 290‡C and is accompanied by formation of amorphous and crystalline phases of CuB24, Cu, and Bam. A crystalline copper phase starts to form at 290‡C.
Databáze: Supplemental Index