| Autor: |
Chkanikov, N. D., Sviridov, V. D., Zelenin, A. E., Galakhov, M. V., Kolomiets, A. F., Fokin, A. V. |
| Zdroj: |
Russian Chemical Bulletin; February 1990, Vol. 39 Issue: 2 p323-328, 6p |
| Abstrakt: |
C-Hydroxyalkylation of primary arylamines by highly electrophilic polyfluorocarbonyl compounds results from the direct reaction of the initial reagents and is competitively inhibited by equilibrium N-hydroxyalkylation. The presence of steric hindrances to the formation of N-hydroxyalkylation products and an increase in the ring C-nucleophilicity facilitate the C-hydroxyalkylation reaction. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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