Autor: |
Orlinkov, A. V., Akhrem, I. S., Vitt, S. V., Afanas'eva, L. V., Zakharkin, L. I., Ovseenko, S. T., Vol'pin, M. E. |
Zdroj: |
Russian Chemical Bulletin; February 1990, Vol. 39 Issue: 2 p290-293, 4p |
Abstrakt: |
It has been shown that AcBr·mAlBr3 complexes (m=1.8–2.0) effectively initiate the isomerization of C12H20 tricyclanes into a mixture of dimethyl- and ethyladamantanes. A quantitative conversion of the starting material is achieved in 3–5 min at room temperature, the overall yield of alkyladamantanes AdC2 amounting to 71–76%. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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