Photoelectron spectra and steric structure of sulfenamides

Autor: Zverev, V. V., Vakar', V. M., Titova, Z. S., Musin, B. M., Ivanov, V. B.
Zdroj: Russian Chemical Bulletin; January 1990, Vol. 39 Issue: 1 p65-69, 5p
Abstrakt: According to the data from photoelectron and UV spectroscopy, the molecules of N,N-dimethylmethane sulfenamide and N,N-diethylpropane-2-sulfenamide have a conformation with orthogonal orientation of nN and nS orbitals, while N,N-dimethylbenzene sulfenamide in the gas phase exists in conformational equilibrium of the planar and skewed conformers.
Databáze: Supplemental Index