31P CIDNP in the reaction of zinc diisopropyldithiophosphate with methyl ethyl ketone peroxide and cumene hydroperoxide in benzene

Autor:	Gainullin, R. M., Ismaev, I. É., Il'yasov, A. V.
Zdroj:	Russian Chemical Bulletin; October 1989, Vol. 38 Issue: 10 p2029-2032, 4p
Abstrakt:	The free-radical nature of the reactions of a series of dithiophosphate complexes of zinc with peroxides was established by31P chemically induced dynamic nuclear polarization (CIDNP). The polarization coefficient, the reaction rate constant, and the nuclear relaxation rate were determined. The dependence of the polarization coefficient on the intensity of the external magnetic field was established.
Databáze:	Supplemental Index
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