| Autor: |
Sviridov, V. D., Chkanikov, N. D., Galakhov, M. V., Kolomiets, A. F., Fokin, A. V. |
| Zdroj: |
Russian Chemical Bulletin; April 1990, Vol. 39 Issue: 4 p853-855, 3p |
| Abstrakt: |
Methyl trifluoropyruvate (II) reacts with phenylhydrazine andp-nitrophenylhydrazine to give the corresponding phenylhydrazones (III) and (IV). The reaction of phenylhydrazine with hexafluoroacetone (I) at 20°C leads to the product of the C2-hydroxyalkylation of the aromatic ring (V). The hydroxyalkylation of hydrazobenzene under the same conditions is complicated by a benzidine rearrangement. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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