Catalytic properties of polyvanadomolybdic acids in oxidation of 1,2,4-trimethylbenzene by peracetic acid

Autor: Petrov, L. A., Lobanova, N. P., Volkov, V. L., Zakharova, G. S., Kolenko, I. P., Buldakova, L. Yu.
Zdroj: Russian Chemical Bulletin; September 1989, Vol. 38 Issue: 9 p1806-1809, 4p
Abstrakt: Polyvanadomolybdic acids catalyze the process of peracid oxidation of 1,2,4-trimethylbenzene. The selectivity with respect to 2,3,5-trimethyl-1,4-benzoquinone increases with increasing degree of replacement of vanadium atoms in the PVMA by molybdenum; this is related to increased stability of the intermediate peroxides of the heteropolyvanadates.
Databáze: Supplemental Index