Molecular structure of perfluoroolefin derivatives. 2. X-ray structural study of 3-p-cresoxyperfluoro-2-methylpent-2-ene

Autor: Sereda, S. V., Antipin, M. Yu., Gervits, L. L., Makarov, K. N., Struchkov, Yu. T.
Zdroj: Russian Chemical Bulletin; July 1989, Vol. 38 Issue: 7 p1416-1419, 4p
Abstrakt: Features of the molecular geometry of 3-p-cresoxyperfluoro-2-methylpent-2-ene are established by x-ray structural studies. Opposing steric and electronic effects of the bulky and electronegative RF-substituents on the C atoms of the double bond in the perfluoroolefins are shown practically not to change the double bond length in comparison with ethylene.
Databáze: Supplemental Index