Reductive defluorination of hexafluoroacetone and the synthesis of halopentafluoroacetones

Autor: Postovoi, S. A., Vol'pin, I. M., Mysov, E. I., Zeifman, Yu. V., German, L. S.
Zdroj: Russian Chemical Bulletin; May 1989, Vol. 38 Issue: 5 p1067-1070, 4p
Abstrakt: 1.Hexafluoroacetone undergoes reductive defluorination upon the action of metals to form perfluoro-2-propenolates of the metals and the products of their subsequent transformations.2.A new preparative method was proposed for the synthesis of pentafluoro-2-propenol and halopentafluoroacetones based on the reaction of hexafluoroacetone with aluminum.
Databáze: Supplemental Index