Relative reactivities of double bonds in compounds with functional groups towards the dimethylcyanomethyl radical

Autor: Markevich, I. N., Borisova, G. S., Glebova, N. N., Sharaev, O. K., Ostrovskaya, I. Ya., Gol'berg, A. I.
Zdroj: Russian Chemical Bulletin; April 1989, Vol. 38 Issue: 4 p789-792, 4p
Abstrakt: 1.The relative reactivities of the double bonds in some unsaturated compounds towards dimethylcyanomethyl radicals have been determined.2.Norbornenes with electron-acceptor substituents (bicyclo[2.2.1]-hept-5-ene-2,3-dicarboxylic acid and its anhydride and imide, and bicyclo[2.2.1]hept-5-ene-2-carbonamide) were more reactive towards these radicals than unsubstituted norbornene.3.The condensation products of maleic anhydride and furfural with p-aminobenzoic acid and its amide, p-aminophenol, etc. are as reactive as acceptors of dimethylcyanomethyl radicals as the original maleic anhydride and furfural.
Databáze: Supplemental Index
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