Conformational investigations of vinyl esters on the basis of spatial effects in multinuclear EPR spectroscopy (1H,13C,15N,17O) and quantum-chemical calculations

Autor: Afonin, A. V., Vashchenko, A. V., Voronov, V. K., Andriyankov, M. A., Ehikeeva, E. I., Garashchenko, Z. M., Mansurov, Yu. A.
Zdroj: Russian Chemical Bulletin; April 1989, Vol. 38 Issue: 4 p776-784, 9p
Abstrakt: 1.The vinyl esters exist predominantly in the S-trans conformation with a syn orientation: of the vinyl and carbonyl group, which is stabilized by a weak C-H...O intramolecular hydrogen bond with the participation of the a proton of the vinyl group.2.In the vinyl ester of picolinic acid the carbonyl group exists predominantly in the S-trans-(N) conformation; in the vinyl ester of nicotinic acid the carbonyl group exists in both the S-cis-(N) and S-trans conformations; in the vinyl ester of furan-2-carboxylic acid the carbonyl group has a predominantly S-cis(O) conformation.
Databáze: Supplemental Index