Autor: |
Afonin, A. V., Vashchenko, A. V., Voronov, V. K., Andriyankov, M. A., Ehikeeva, E. I., Garashchenko, Z. M., Mansurov, Yu. A. |
Zdroj: |
Russian Chemical Bulletin; April 1989, Vol. 38 Issue: 4 p776-784, 9p |
Abstrakt: |
1.The vinyl esters exist predominantly in the S-trans conformation with a syn orientation: of the vinyl and carbonyl group, which is stabilized by a weak C-H...O intramolecular hydrogen bond with the participation of the a proton of the vinyl group.2.In the vinyl ester of picolinic acid the carbonyl group exists predominantly in the S-trans-(N) conformation; in the vinyl ester of nicotinic acid the carbonyl group exists in both the S-cis-(N) and S-trans conformations; in the vinyl ester of furan-2-carboxylic acid the carbonyl group has a predominantly S-cis(O) conformation. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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