Mechanism of haptotropic rearrangements in the chromium tricarbonyl complexes of naphthalene and its analogs

Autor: Oprunenko, Yu. F., Malyugina, S. G., Trifonova, O. I., Babushkina, O. Ya., Pisarevskii, A. P., Ustynyuk, Yu. A., Ustynyuk, N. A., Kravtsov, D. N., Nesterenko, P. N.
Zdroj: Russian Chemical Bulletin; February 1988, Vol. 37 Issue: 2 p357-360, 4p
Abstrakt: 1.The haptotropic rearrangements in the chromium tricarbonyl complexes of 1-methylacenaphthene take place predominantly with retention of the stereochemistry, i.e., the exo-and endo-configuration of the interconverting complexes is preserved during the rearrangement.2.The mechanism of the rearrangements observed in the chromium tricarbonyl complexes of naphthene and its analogs was established. It involves intramolecular migration of the organometallic group betwen the six-membered rings.
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