Reaction of the ethyl radical with toluene as the major pathway for the formation of aluminum-free products in the reaction of (C2H5O)2AlC2H5 with XeF2

Autor:	Bulgakov, R. G., Yakovlev, V. N., Popov, Yu. N., Tolstikov, G. A., Kazakov, V. P.
Zdroj:	Russian Chemical Bulletin; December 1987, Vol. 36 Issue: 12 p2489-2492, 4p
Abstrakt:	1.Aluminum-free products are formed in the reaction of aluminum alkyl compounds with XeF2 due to the reaction of alkyl radicals with the solvent.2.A free-radical mechanism for the reaction of the organoaluminum alkyl compounds with XeF2 was established relative to the inhibition of chemiluminescence and gas liberation process.3.Chemiluminescence was detected upon the reaction of the galvinoxyl inhibitor with XeF2 accompanied by the liberation of gaseous xenon.
Databáze:	Supplemental Index
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