| Autor: |
Yasman, Yu. B., Sangalov, Yu. A., Ponedel'kina, I. Yu., Khusnutdinov, R. I., Dokichev, V. A., Dzhemilev, U. M., Tolstlkov, G. A. |
| Zdroj: |
Russian Chemical Bulletin; March 1988, Vol. 37 Issue: 3 p553-556, 4p |
| Abstrakt: |
1.2-Hydroxymethylbicyclo[2.2.1]2,5-heptadiene effects protolysis of only one of the Al-C bonds in organoaluminum compounds. The composition and structures of the protolysis products have been established based on1H- and13C-NMR data, UV spectroscopy, and cryoscopic and volumetric analysis, which have also provided evidence for the formation of intramolecular complexes.2.Reaction of 2-hydroxymethylbicyclo[2.2.1]2,5-heptadiene with organoaluminum compounds does not change the electronic state of the double bond at C5. The reaction product is of interest as a monomer containing a protected polar functional group. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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