| Autor: |
Kaiin'sh, K. K., Toropov, D. K., Shchukareva, V. V. |
| Zdroj: |
Russian Chemical Bulletin; March 1987, Vol. 36 Issue: 3 p512-516, 5p |
| Abstrakt: |
1.Incorporation of solvent molecules in the crystalline complex of benzidine (B) with tetracyanoquinomethane (TCQ): B-TCQ, affects the value of the charge transfer energies as a function of the change in the B-TCQ interplanar distances. The decrease in the charge transfer energies is due to the formation of a H bond in the excited state of the complex.2.The paramagnetism of B-TCQ complexes is primarily determined by the TCQ-· anion radicals which arise during the electron transfer reaction. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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