Liquid phase oxidation of transition metals. Communication 8. dissolution of chromium in the ccl4-alcohol system

Autor: Chulkevich, A. K., Korableva, L. G., Lavrent'ev, I. P., Ponomarev, V. I., Khidekel', M. L.
Zdroj: Russian Chemical Bulletin; March 1986, Vol. 35 Issue: 3 p610-613, 4p
Abstrakt: 1.Oxidation of chromium in the alcohol-carbon tetrachloride-tetramethyl urea or tetramethyl sulfone systems yields [NH2Me2]4[CrCl6]Cl, CrCl3·2[(CH2)4SO2]·3H2O, CrCl3·4MeOH·H2O, and CrCl3·1.75EtOH·2.5H2O.2.The molecular and crystal structure of the complex [NH2Me2]4[CrCl6]Cl was determined by x-ray diffraction analysis.
Databáze: Supplemental Index