Oxidative cleavage of cycloalkanones by hydrogen peroxide

Autor: Starostin, E. K., Aleksandrov, A. V., Nikishin, G. I.
Zdroj: Russian Chemical Bulletin; January 1986, Vol. 35 Issue: 1 p72-75, 4p
Abstrakt: 1.Oxidation of cyclohexanone by aqueous hydrogen peroxide at 110–150°C gives 1,10-decanedicarboxylic acid and hexanoic acid as the principal products.2.Cyclopentanone and cycloheptanone react with hydrogen peroxide similarly to cyclohexanone, giving sebacic and pentanoic acids, and 1,12-dodecanedicarboxylic acids, respectively.
Databáze: Supplemental Index