Mechanism of the oxidation of acetylacetone by hydrogen peroxide, catalyzed by Mo(VI) complexes

Autor: Gekhman, A. E., Nekipelov, V. M., Sakharov, S. G., Zamaraev, K. I., Moiseev, I. I.
Zdroj: Russian Chemical Bulletin; June 1986, Vol. 35 Issue: 6 p1126-1130, 5p
Abstrakt: 1.Oxidation of the acetylacetonate ion in the coordination sphere of molybdenum(VI) by hydrogen peroxide proceeds without the participation of paramagnetic particles, recordable by steady-state ESR methods.2.It was established by the PMR method that the oxidation of 2,4-pentanedione by hydrogen peroxide in the presence of sodium molybdate proceeds through intermediate formation of the complex of Mo(VI) with 3,3-dihydroxy-2,4-pentanedione.3.A complex of Mo(VI) with 3,3-dihydroxy-2,4-pentanedione was produced for the first time.
Databáze: Supplemental Index
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