Complex of vanadium(5+) with the dioxygen radical-anion in the catalyzed disproportionation of hydrogen peroxide

Autor: Makarov, A. P., Gekhman, A. E., Nekipelov, V. M., Talzi, E. P., Polotnyuk, O. Ya., Zamaraev, K. I., Moiseev, I. I.
Zdroj: Russian Chemical Bulletin; August 1985, Vol. 34 Issue: 8 p1764-1767, 4p
Abstrakt: The intermediate formation of vanadium(5+) peroxo complexes was detected under conditions of the disproportionation of hydrogen peroxide in acetic acid catalyzed by ammonium metavanadate by51V NMR spectroscopy and the complex of vanadium(5+) ions with the dioxygen radical-anion was detected by ESR spectroscopy.
Databáze: Supplemental Index