| Autor: |
Dermugin, V. S., Shvedov, V. I., Litvinov, V. P. |
| Zdroj: |
Russian Chemical Bulletin; November 1985, Vol. 34 Issue: 11 p2362-2366, 5p |
| Abstrakt: |
1.3-(1-Adamantyl)-2-methyl-3-chloropropenal has been synthesized for the first time by chloroformylation of 1-adamantyl ethyl ketone. It is a convenient synthon for obtaining o-methyl-substituted heteryladamantanes.2.3-(1-Adamantyl)-2-methyl-3-chloropropenal is formed as a mixture of Z and E isomers with the latter predominating [in contrast to the Z form of 3-(1-adamantyl)-3-chloropropenal].3.Similarities and differences in the characteristics of 3-(1-adamantyl)-2-methyl-3-chloropropenal and 3-(1-adamantyl)-3-chloropropenal are discussed. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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