Synthesis and spectroscopic study of trans complexes of Pd(II) with the 4-amino-2,2,6,6-tetramethylpiperidine-1-oxyl radical

Autor: Zakharova, I. A., Kurbakova, A. P., Ivanova, N. A., Lokshin, B. V., Prokofev, A. I.
Zdroj: Russian Chemical Bulletin; September 1985, Vol. 34 Issue: 9 p1963-1969, 7p
Abstrakt: 1.Complexes of Pd(II) with the 4-amino-2,2,6,6-tetramethylpiperidine-1-oxyl radical (L) with the composition L2PdX2 (X=Cl, Br) have been synthesized.2.It has been shown by the methods of vibrational and Raman speetroscopy that these complexes are biradicals and have the trans structure of the central coordination node PdN2X2.
Databáze: Supplemental Index