Conversion of 4-hydroxy-3,5-di-tert-butylbenzonitrile to palladium and rhodium complexes

Autor: Rubezhov, A. Z., Milaeva, E. R., Prokof'ev, A. I., Karsanov, I. V., Okhlobystin, O. Yu.
Zdroj: Russian Chemical Bulletin; May 1984, Vol. 33 Issue: 5 p1049-1052, 4p
Abstrakt: Conclusions Complexes of palladium (II) and rhodium (III) with 4-hydroxy-3,5-di-tert-butylbenzo-nitrile have been synthesized and it has been found that during their oxidation the metal-ligand bond is broken to yield the free nitrilophenoxyl radical in solution which under the action of the transition metal salt undergoes cyclotrimerization with formation of the non-symmetrical triazine.
Databáze: Supplemental Index