Reaction of α-alkoxyacroleins with semicarbazide and its S-, Se-, and NH-analogs

Autor: Keiko, N. A., Mamashvili, T. N., Rassolova, G. V., Kashik, T. V., Kalikhman, I. D., Vbronkov, M. G.
Zdroj: Russian Chemical Bulletin; March 1984, Vol. 33 Issue: 3 p561-564, 4p
Abstrakt: Conclusions 1.The reaction ofa-alkoxyacroleins with semi-, thiosemi-, and selenosemicarbazides in a basic medium leads to the formation of semi-, thiosemi-, and selenosemicarbazones ofa-alkoxyacrolein. The reactions of a-ethoxyacroleins with twofold excess amounts of semi- and selenosemicarbazides in acid media lead to disemi- and diselenosemicarbazones of methylglyoxal.2.Determination of basicity constants of semicarbazide and its S-, Se-, and NH-analogs was carried out in acetonitrile.
Databáze: Supplemental Index