Hydrosilylation of organosilicon acetylenic carbonyl compounds

Autor: Pukhnarevich, V. B., Tsykhanskaya, I. I., Voronkov, M. G.
Zdroj: Russian Chemical Bulletin; February 1984, Vol. 33 Issue: 2 p390-392, 3p
Abstrakt: The H2PtCl6-catalyzed hydrosilylation of organosilicon acetylenic carbonyl compounds Me3SiC=CCOR (R=H, Me, Ph) with triethylsilane (XH) leads in moderate yield to the formation of the regioisomeric adducts Me3SiCH=CXCOR and Me3 SiCX=CHCOR in a 5:1 mole ratio.
Databáze: Supplemental Index