Asymmetric aminoacid synthesis by catalytic reduction of azlactones of substituted acylaminoacrylic acids Communication 17. Reaction of PdCl2 with S-(-)-α-phenylmethylamine under reducing conditions

Autor: Karpeiskaya, E. I., Godunova, L. F., Levitina, E. S., Lyubeznova, M. R., Klabunovskii, E. I., Lubuzh, E. D., Lutsenko, A. I.
Zdroj: Russian Chemical Bulletin; January 1984, Vol. 33 Issue: 1 p73-78, 6p
Abstrakt: When PdCl2 is reduced by hydrogen in the presence of S-(-)-a-phenylethylamine in chloroform, zero-valent complexes of Pd with S-(-)-a-phenylethylamine are formed. These are enantioselective catalysts for the reductive aminolysis of the azlactones of dehydroacyl-aminoacids.
Databáze: Supplemental Index