Synthesis and conversions of η5-chloromethylcyclopentadienyltricarbonylrhenium

Autor: Valueva, Z. P., Solodova, M. Ya., Kolobova, N. E.
Zdroj: Russian Chemical Bulletin; August 1983, Vol. 32 Issue: 8 p1687-1690, 4p
Abstrakt: Conclusions 1.The chloromethylation of η5-cyclopentadienyltricarbonylrhenium by chloromethyl ether in the presence of AlCl3 has been investigated.2.The exchange of hydroxyl by chlorine in η5-hydroxymethylcyclopentadienyltricarbonylrhenium has been effected.3.Alkylation of ν5-cyclopentadienyltricarbonylrhenium by ν5-chloromethylcyclopentadienyltricarbonylrhenium has been carried out under conditions of the Friedel-Crafts reaction.4.The hydrolysis of ν5-chloromethylcyclopentadienyltricarbonylrhenium has been investigated.
Databáze: Supplemental Index