Hydrogermylation of 1,3-dienes using nickel catalyst systems

Autor: Salimgareeva, I. M., Bogatova, N. G., Panasenko, A. A., Khalilov, L. M., Purlei, I. I., Mavrodiev, V. K., Yur'ev, V. P.
Zdroj: Russian Chemical Bulletin; July 1983, Vol. 32 Issue: 7 p1456-1461, 6p
Abstrakt: 1.A study was carried out on the hydrogermylation of 1,3-dienes by triethylgermane using nickel catalyst systems. The reaction of substituted 1,3-dienes and triethylgermane proceeds selectively by 1,4-cis-addition. The hydrogermylation of butadiene is accompanied by the formation of a series of octadienyl derivatives.2.The optimal conditions were found for the preparation of HGeEt3 by the reduction of Et3GeI.
Databáze: Supplemental Index