Catalytic properties of group VIII metal compounds supported on a polymeric carrier

Autor: Sukhobok, L. N., Potapov, G. P., Polkovnikov, B. D., Luksha, V. G., Krutii, V. N.
Zdroj: Russian Chemical Bulletin; April 1983, Vol. 32 Issue: 4 p763-764, 2p
Abstrakt: 1.Nickel and cobalt complexes supported on a polymeric carrier containing phosphinate or phosphonate groups catalyze the hydrogenation and isomerization of allylbenzene. Nickel complexes were more active than cobalt complexes.2.A reduction in the electron-accepting properties of the substituent on the phosphorus atom promoted an increase in the catalytic activity of the synthesized systems. Complexes containing a cyclohexyloxy substituent on the phosphorus atom displayed the greatest activity.
Databáze: Supplemental Index