New method for the stabilization of intermediate radicals in the reaction of thiourea and its N-substituted derivatives with phenyl radicals

Autor: Freidlina, R. Kh., Kopylova, B. V., Kandror, I. I., Yashkina, L. V.
Zdroj: Russian Chemical Bulletin; April 1983, Vol. 32 Issue: 4 p801-805, 5p
Abstrakt: The reaction of thiourea, N-phenyl-, and N,N'-diphenylthiourea with phenyl radicals proceeds by two competing pathways with the formation of the corresponding S-phenylisothiouronium compounds and bis(formamidine) sulfides. The ratio of the product yields depends on the nature of the thiourea, radical precursors, and reaction conditions.
Databáze: Supplemental Index